全文获取类型
收费全文 | 20140篇 |
免费 | 2219篇 |
国内免费 | 861篇 |
专业分类
电工技术 | 1025篇 |
综合类 | 2521篇 |
化学工业 | 4124篇 |
金属工艺 | 1126篇 |
机械仪表 | 833篇 |
建筑科学 | 1134篇 |
矿业工程 | 561篇 |
能源动力 | 1743篇 |
轻工业 | 1166篇 |
水利工程 | 419篇 |
石油天然气 | 359篇 |
武器工业 | 77篇 |
无线电 | 1708篇 |
一般工业技术 | 2489篇 |
冶金工业 | 428篇 |
原子能技术 | 218篇 |
自动化技术 | 3289篇 |
出版年
2024年 | 62篇 |
2023年 | 1082篇 |
2022年 | 957篇 |
2021年 | 1030篇 |
2020年 | 1328篇 |
2019年 | 1029篇 |
2018年 | 668篇 |
2017年 | 1085篇 |
2016年 | 1203篇 |
2015年 | 1045篇 |
2014年 | 1484篇 |
2013年 | 1436篇 |
2012年 | 1507篇 |
2011年 | 1501篇 |
2010年 | 1178篇 |
2009年 | 1284篇 |
2008年 | 591篇 |
2007年 | 1193篇 |
2006年 | 1113篇 |
2005年 | 511篇 |
2004年 | 278篇 |
2003年 | 261篇 |
2002年 | 309篇 |
2001年 | 247篇 |
2000年 | 194篇 |
1999年 | 224篇 |
1998年 | 110篇 |
1997年 | 65篇 |
1996年 | 54篇 |
1995年 | 46篇 |
1994年 | 26篇 |
1993年 | 33篇 |
1992年 | 30篇 |
1991年 | 14篇 |
1990年 | 8篇 |
1989年 | 7篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 5篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1959年 | 1篇 |
1951年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
Microbiologically influenced corrosion induced by bacteria has been studied for many years. Corrosion is known to be sensitive to the presence of microalgae, such as Phaeodactylum tricornutum. However, the life activity of P. tricornutum that influences the general and localized corrosion of carbon steel is not fully understood. The current study uses a combination of immersion tests and electrochemical experiments with a detailed surface characterization to reveal the naturally formed corrosion products with/without the presence of P. tricornutum. The results show that samples suffer from pitting corrosion and the averaged pit depths are approximately 15 μm under a light–dark cycle condition or a 24-h constant light condition. Meanwhile, the corrosion products are mainly comprised of γ-FeOOH and Fe3O4 in a constant light condition. However, γ-FeOOH, Fe3O4, and FeCO3 are found in a light–dark cycle. This study proposes the fundamental mechanisms of the effect of P. tricornutum life activities on the corrosion performance of Q235 carbon steel, to fulfill the knowledge gaps of the presence of microalgae inducing the general and pitting corrosion of carbon steel. 相似文献
2.
The audit point is to understand and use to perform the upgrade wearable innovation injuries in sports. Understanding the game's biomechanics is that damage response and performance upgrades are essential, and usually, investigation uses optical motion capture. In any case, this approach may be limited by the amount of limit catch climatic factors and the overwhelmed wearable research center of innovation. Ordered to make queries are used to study in seven information centers and sports car wearable innovation factors. This article was banned because they do not measure the program members on the sensor zero and the motor or motor factors or the application of an innovative set. Thirty-three incorporated into the collection of the full text of the survey carried out to identify members' dynamic development through observation and a slice of wearable progress in the game. Inertial sensors, the sensor and the flexible, attractive and precise speed field sensors are used in the game with more than 15 measured motion gadgets. The use of wearable innovation, the potential of these innovative practices, and the impact of competitors' training methods are still in the exploratory stage. 相似文献
3.
Kong Xiang-wei Zhang Chao-ju Jin Yan-xin Liu Ming-gang Sun Teng-fei 《Chemistry and Technology of Fuels and Oils》2021,57(5):865-869
Chemistry and Technology of Fuels and Oils - At present, the wellbore overflow in a fractured gas reservoir is mainly characterized by qualitative methods. The development of quantitative methods... 相似文献
4.
5.
《Journal of the European Ceramic Society》2021,41(13):6596-6605
This work focuses on identifying the rate-determining step of oxygen transport through La0.5Sr0.5Fe0.7Ga0.3O3-δ membranes with symmetric and asymmetric architectures. The best oxygen semipermeation fluxes are 3.4 10−3 mol. m-2.s-1 and 6.3 10−3 mol. m-2.s-1 at 900 °C for the symmetric membrane and asymmetric membrane with a modified surface. The asymmetric membrane with a modified surface leads to an increase of approximately 7 times the oxygen flux compared to that obtained with the La0.5Sr0.5Fe0.7Ga0.3O3-δ dense membrane without surface modification. This work also shows that the oxygen flux is mainly governed by gaseous oxygen diffusion through the porous support of asymmetric La0.5Sr0.5Fe0.7Ga0.3O3-δ membranes. 相似文献
6.
Yuanyuan Chen Jian Peng Tian Sheng Ruixuan Qin Shuqi Dai Zaifa Shi Zichao Tang Laisen Wang Qinghua Zhang Bin Han Liping Sun Jun Xu Jian Weng 《Advanced functional materials》2021,31(42):2104246
Radicals are closely related to human life and health and have been widely used in biology, chemistry, functional materials, etc. However, the high reactivity, disorder, and short half-lives limit their wide applications. Therefore, it remains a great challenge to prepare stable and ordered radicals. Herein, radicals are prepared with protective umbrellas (diethylmethyleneamine, DEMA) that are integrated on the surface of 2D layered materials to isolate water and oxygen and enhance the stability of radicals. Taking 2D black phosphorus (BP) as an example: triethylamine reacts with dichloromethane to form quaternary ammonium salts with further Hoffmann elimination to produce DEMA radicals that could react with one electron of a lone pair electrons in P on the surface of BP to produce P radicals, which shows a prolonged half-life of 21 days at room temperature. First-principle calculations and electron paramagnetic resonance fitting confirm that the steric hindrance constructed by dense DEMA passivation layer acts as a protective umbrella and the 2D coupling of P radicals and other P atoms in 2D BP plane to enhance the stability and strong superexchange interaction of P radicals. Furthermore, it is a general strategy to produce stable radicals integrated on the 2D plane. 相似文献
7.
《Mechatronics》2022
In this paper, dual control moment gyroscopic actuators (CMG) were formed in a scissored-pair configuration to maximize the induced torque in the desired direction. A robust synchronizing motion control method was proposed to regulate the directional gyroscopic torque. In order for the two CMGs to form a scissored-pair structure having opposite angular momentum vectors, the synchronization of two CMGs was done without losing the control capability due to axial drift. A transformation matrix was designed for the robust synchronization control performance by realizing the empirically discovered impedance models of CMGs. Three different control modes were realized by selecting the components of the impedance transformation matrix (ITM): a robustly independent control mode, a synchronized motion control mode, and a mixed motion control mode. Each CMG played the role of either a master or a slave and copied the motion from another to follow it under the synchronization mode. The experimental results show that two CMGs can generate a robust and directional torque under the mixed control mode of both robust and synchronization control. 相似文献
8.
Additive manufacturing,quasi-static and dynamic compressive behaviours of ceramic lattice structures
《Journal of the European Ceramic Society》2022,42(15):7102-7112
Ceramic lattice structures (CLSs) are used for construction in common and extreme environments because of the extraordinary properties of ceramics. In this study, we designed and additively manufactured CLSs with distinct structural parameters to explore their quasi-static and dynamic compressive behaviours in detail. It was demonstrated that both the relative density (?ρ) and inclination angle (ω) had a significant impact on the quasi-static and dynamic mechanical properties of the CLSs. Furthermore, the mathematical relationships between the quasi-static compressive properties, including quasi-static compressive strength (QS), quasi-static Young’s modulus (QY), and quasi-static energy absorption (QE), versus ?ρ and ω obeyed the Gibson–Ashby and Deshpande and Fleck models, respectively. It was revealed by experiment and simulation that as the stiffness increased, the quasi-static failure mode of the CLSs changed from a parallel-vertical-inclined mixed mode to a parallel-vertical mode. In addition, the relationship between the dynamic mechanical properties of the CLSs versus ?ρ and ω also followed the Gibson–Ashby and Deshpande and Fleck models. The exceptional dynamic increase factor indicated that CLSs are highly suitable for extreme environments. These findings will aid in the research and development of customised additively manufactured CLSs. 相似文献
9.
《International Journal of Hydrogen Energy》2022,47(4):2608-2621
On-site produced hydrogen from ammonia decomposition can directly fuel solid oxide fuel cells (SOFCs) for power generation. The key issue in ammonia decomposition is to improve the activity and stability of the reaction at low temperatures. In this study, proton-conducting oxides, Ba(Zr,Y) O3-δ (BZY), were investigated as potential support materials to load Ni metal by a one-step impregnation method. The influence of Ni loading, Ba loading, and synthesis temperature, of Ni/BZY catalysts on the catalytic activity for ammonia decomposition were investigated. The Ni/BZY catalyst with Ba loading of 20 wt%, Ni loading of 30 wt%, and synthesized at 900 °C attained the highest ammonia conversion of 100% at 600 °C. The kinetics analysis revealed that for Ni/BZY catalyst, the hydrogen poisoning effect for ammonia decomposition was significantly suppressed. The reaction order of hydrogen for the optimized Ni/BZY catalyst was estimated as low as ?0.07, which is the lowest to the best of our knowledge, resulting in the improvement in the activity. H2 temperature programmed reduction and desorption analysis results suggested that a strong interaction between Ni and BZY support as well as the hydrogen storage capability of the proton-conducting support might be responsible for the promotion of ammonia decomposition on Ni/BZY. Based on the experimental data, a mechanism of hydrogen spillover from Ni to BZY support is proposed. 相似文献
10.
《Ceramics International》2022,48(22):33122-33134
Gradient refractive index (GRIN) micro-optics present unique opportunities for control of the chromatic properties, new degrees of freedom for optical design as well as the potential for use in new optical system applications. GRIN microgratings were imprinted in GeS2-Ga2S3-MCl (M = Na, K, Cs) chalcohalide glasses by microthermal poling, and the effects of the type and concentration of alkali cations on their performance were investigated. Two effective imprinting formation regions of the GRIN microstructure based on the poling saturation voltage (Us) and glass composition are observed at fixed poling time and temperature. The Us increases from 140 to 750 and 2600 V in accordance with the activation energy (Ea) of alkali ions (Na+ to K+ and Cs+) increasing from 45.15 to 58.62 and 92.58 kJ/mol for studied samples. The saturated numbers of diffraction order (Ns) of the gratings in these samples are 7, 9 and 6, respectively, the highest number being provided by the K+-containing sample. This is in accordance with imprinting-induced phase differences (0.14λ, 0.19λ and 0.09λ) measured in the fabricated samples containing Na+, K+ and Cs+ ions. Furthermore, the Us of samples decreases from 1500 to 300 V with four concentrations of K+ from 10 to 30%, associated with their Ea of K+ decreasing from 69.62 to 53.46 kJ/mol, while Ns increases from 8 to 14, which is attributed to the increase of the phase difference in the GRIN structures. The controllable GRIN microstructures are realized by adjusting the type and concentration of alkali cations in chalcohalide glasses, which is expected to drive the design of broadband GRIN microgratings. 相似文献